Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles.
نویسندگان
چکیده
Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 126 26 شماره
صفحات -
تاریخ انتشار 2004